期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 42, 页码 17466-17469出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3085093
关键词
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资金
- Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy [DE-FG02-04ER15591]
A molecular triad assembly consisting of an electron donor, a bis(phenanthroline)copper(I) chromophore, and an electron acceptor has been prepared. Under visible-light excitation, this assembly undergoes efficient (ca. 50%) photoinduced, multistep formation of a diradical cation charge-separated state that has a lifetime of >100 ns and stores >1.0 eV of energy. This system constitutes an earth-abundant functional analogue of related Ru(bpy)(3) triad systems.
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