期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 26, 页码 10783-10786出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja304255h
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- University of Illinois at Chicago
An efficient 1,4-hydrovinylative cyclization reaction of triynes and tetraynes catalyzed by ruthenium alkylidene complexes under ethylene is described. The regioselectivity of vinyl group incorporation can be controlled by the nature of the substituent on the alkyne, and the Grubbs second-generation catalyst is the most effective among typical ruthenium alkylidene complexes.
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