期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 6, 页码 2856-2859出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja208668u
关键词
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资金
- National Institutes of Health [GM54623]
- Royal Society
The bismuth-mediated two-component hemiacetal/oxa-conjugate addition of delta-trialkylsilyloxy and delta-hydroxy alpha,beta-unsaturated aldehydes and ketones with alkyl aldehydes provides the syn-1,3-dioxanes in a highly efficient and stereoselective manner. The key advantages of this protocol are its operational simplicity and its ability to directly access electron-withdrawing groups without recourse to oxidation state adjustments.
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