期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 46, 页码 18944-18947出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja309947n
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资金
- NIGMS NIH HHS [GM 033049, R01 GM033049] Funding Source: Medline
The first total synthesis of aeruginosin 98B was accomplished. The key step is a highly diastereoselective Pd-catalyzed intramolecular asymmetric allylic alkylation reaction of a diastereomeric mixture of allylic carbonates that is enabled by the use of racemic phosphine ligand L1.
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