4.8 Article

NH2-MIL-53(Al): A High-Contrast Reversible Solid-State Nonlinear Optical Switch

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 20, 页码 8314-8317

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AMER CHEMICAL SOC
DOI: 10.1021/ja300655f

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  1. FWO (Belgium)
  2. Belgian Prodex Office
  3. Flemish Government (Methusalem)
  4. Dutch National Science Foundation (NWO-CW-VENI)

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The metal organic framework NH2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

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