期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 20, 页码 8314-8317出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja300655f
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资金
- FWO (Belgium)
- Belgian Prodex Office
- Flemish Government (Methusalem)
- Dutch National Science Foundation (NWO-CW-VENI)
The metal organic framework NH2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.
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