期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 36, 页码 14236-14239出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja206286h
关键词
-
资金
- National Science Foundation [CHE-0617063, CHE-1010002]
- Direct For Mathematical & Physical Scien [1111900, 1010002] Funding Source: National Science Foundation
- Division Of Chemistry [1010002, 1111900] Funding Source: National Science Foundation
The synthesis and magnetic properties of three new N-2(3-) radical-bridged dilanthanide complexes, {[(Me3SO2N](2)(THF)Ln}(2)(mu-eta(2):eta(2)-N-2)(-) (Ln = Tb, Ho, Er), are reported. All three display signatures of single-molecule-magnet behavior, with the terbium congener exhibiting magnetic hysteresis at 14 K and a 100 s blocking temperature of 13.9 K. The results show how synergizing the strong magnetic anisotropy of terbium(III) with the effective exchange-coupling ability of the N-2(3-) radical can create the hardest molecular magnet discovered to date. Through comparisons with non-radical-bridged ac magnetic susceptibility measurements, we show that the magnetic exchange coupling hinders zero-field fast relaxation pathways, forcing thermally activated relaxation behavior over a much broader temperature range.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据