期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 47, 页码 19102-19109出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2049463
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [20360340]
- National Natural Science Foundation of China [10904145, 10974203]
- Anhui Natural Science Foundation [090414188]
- Grants-in-Aid for Scientific Research [23350101, 21110004, 23760701, 20360340] Funding Source: KAKEN
A general synthesis of inorganic single-crystalline hollow spheres has been achieved through a mechanism analogous to the Kirkendall effect, based on a simple one-step laser process performed at room temperature. Taking TiO2 as an example, we describe the laser process by investigating the influence of experimental parameters, for example, laser wavelength, laser fluence/irradiation time, liquid medium, and concentration of starting materials, on the formation of hollow spheres. It was found that the size-tailored TiO2 hollow spheres demonstrate tunable light scattering over a wide visible-light range. Inspired by the effect of light scattering, we introduced the TiO2 hollow sphere's scattering layer in quantum dot-sensitized solar cells and achieved a current notable 10% improvement of solar-to-electric conversion efficiency, indicating that TiO2 hollow spheres are potential candidates in optical and optoelectronic devices.
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