期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 40, 页码 15938-15941出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja207588c
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- U.S. NSF [CHE 1057904, 0741973]
- R.A. Welch Foundation [F-1018]
- KOSEF/MEST through WCU, Korea [R31-2008-000-10010-0, R32-2010-000-10217-0]
- [20108010]
- [23750014]
- [2010-0029668]
- National Research Foundation of Korea [2005-0093839, R32-2010-000-10217-0, R32-2011-000-10217-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- Grants-in-Aid for Scientific Research [20108010, 20108001] Funding Source: KAKEN
Binding of chloride anion to a tetrathiafulvalene calix[4]pyrrole (TTF-C4P) donor results in ET to Li+@C-60 to produce the radical pair (TTF-C4P(center dot+)/Li+C60 center dot-), the structure of which was characterized by X-ray crystallographic analysis. The addition of tetraethylammonium cation, which binds more effectively than Li+C60 center dot- as a guest within the TTF-C4P cavity, leads to electron back-transfer, restoring the initial oxidation states of the donor and acceptor pair.
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