期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 38, 页码 14916-14919出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja206099t
关键词
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- University of Toronto
- German Academic Exchange Service (DAAD)
Aryl bromides have been used to prepare a variety of nitrogen- and oxygen-containing heterocycles featuring new carbon-carbon and carbon-iodine bonds. This palladium-catalyzed carbohalogenation requires potassium iodide for the reaction to proceed in high yields. Additionally, the first examples of domino carbohalogenation reactions have been demonstrated using both aryl iodide and aryl bromide starting materials. Complex products with multiple rings and stereogenic centers are generated in excellent yields with moderate to excellent diastereoselectivities.
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