期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 40, 页码 15814-15817出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja204562m
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资金
- NSERC
- CFI
- ERA
Bis(imino)pyridine pincer ligands in conjunction with two isothiocyanate ligands have been used to prepare two mononuclear Co(II) complexes. Both complexes have a distorted square-pyramidal geometry with the Co(II) centers lying above the basal plane. This leads to significant spin-orbit coupling for the d(7) Co(II) ions and consequently to slow relaxation of the magnetization that is characteristic of Single-Molecule Magnet (SMM) behavior.
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