期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 45, 页码 18094-18097出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja208408n
关键词
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资金
- National Science Foundation [CHE-0911690, DMR-0805089, CMMI-0963509, CHE-0840518]
- Robert A. Welch Foundation [B-1542]
- U.S. Department of Energy, Office of Science [DE-AC05-00OR22725]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [911690] Funding Source: National Science Foundation
We demonstrate that fluorous metal-organic frameworks (FMOFs) are highly hydrophobic porous materials with a high capacity and affinity to C(6)-C(8) hydrocarbons of oil components. FMOF-1 exhibits reversible adsorption with a high capacity for n-hexane, cyclohexane, benzene, toluene, and p-xylene, with no detectable water adsorption even at near 100% relative humidity, drastically outperforming activated carbon and zeolite porous materials. FMOF-2, obtained from annealing FMOF-1, shows enlarged cages and channels with double toluene adsorption vs FMOF-1 based on crystal structures. The results suggest great promise for FMOFs in applications such as removal of organic pollutants from oil spills or ambient humid air, hydrocarbon storage and transportation, water purification, etc. under practical working conditions.
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