4.8 Article

Ni-Catalyzed Ketene Cycloaddition: A System That Resists the Formation of Decarbonylation Side Products

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 20, 页码 7719-7721

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AMER CHEMICAL SOC
DOI: 10.1021/ja2007627

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资金

  1. DOE
  2. NSF
  3. NIGMS [5R01GM076125]
  4. CNPq-Brasil [201732/2008-4]
  5. Division Of Chemistry
  6. Direct For Mathematical & Physical Scien [0911017] Funding Source: National Science Foundation

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Ni-phosphine complexes were used as catalysts for the cycloaddition of various ketenes and diynes. In general, 2,4-cyclohexadienones were formed instead of products arising from decarbonylation of the ketenes.

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