期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 15, 页码 5806-5809出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja202223d
关键词
-
资金
- MacDiarmid Institute
- RSNZ Marsden Fund
We present a general strategy for incorporating organocatalytic moieties into metal organic frameworks (MOFs). The organocatalytic units are protected by a thermolabile protecting group during MOF synthesis and then unveiled by a simple postsynthetic heating step. The strategy is exemplified using a thermolabile tert-butoxycarbonyl (Boc) protecting group for a proline moiety, the removal of which endows the resulting cubic zinc(II) IRMOF with catalytic activity for asymmetric aldol reactions. The bulky Boc groups also prevent framework interpenetration, producing open MOFs that can admit relatively large substrates.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据