期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 6, 页码 1614-1617出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1076102
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资金
- BBSRC [BBS/S/E/2006/13241]
- EPSRC [EP/F03623X/1]
- Pakistan HEC
- EPSRC [EP/F03623X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F03623X/1] Funding Source: researchfish
Decalins bearing two axial -NHCONHAr substituents and an ester-linked alkyl side chain have been synthesized and studied as anion receptors and transporters. The design relates to steroid-based cholapods but is more compact and less intrinsically lipophilic. Transport rates depend on both NHAr and the alkyl side chain. High activities can be achieved; with optimal substitution, chloride-nitrate exchange across vesicle membranes is measurable at transporter/lipid ratios as low as 1:250000.
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