期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 30, 页码 11478-11481出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja204728y
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资金
- DOE [DE-FG36-08GO18141]
- Japan Society for the Promotion of Science
- KAIST
- National Research Foundation of Korea [R31-2011-000-10055-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Condensation of 2,5-diethoxyterephthalohydrazide with 1,3,5-triformylbenzene or 1,3,5-tris(4-formylphenyl)benzene yields two new covalent organic frameworks, COF-42 and COF-43, in which the organic building units are linked through hydrazone bonds to form extended two-dimensional porous frameworks. Both materials are highly crystalline, display excellent chemical and thermal stability, and are permanently porous. These new COFs expand the scope of possibilities for this emerging class of porous materials.
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