期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 15, 页码 5767-5769出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2010225
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资金
- National Institutes of Health (NIGMS) [1 R01 GM084019-01A1]
- National Science Foundation under the Center of Chemical Innovation in Stereoselective C-H Functionalization [CHE-0943980]
- Amgen
- China Scholarship Council
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0943980] Funding Source: National Science Foundation
The total synthesis of (+)-lithospermic acid is reported, which exploits two successive C-H activation reactions as key steps. Rh-catalyzed carbene C-H insertion reaction utilizing Davies's catalyst was used to forge dihydrobenzofuran core, and a late-stage intermolecular C-H olefination coupled the olefin unit with the dihydrobenzofuran core to construct the molecule in a highly convergent manner.
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