期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 14, 页码 5248-5251出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja201245s
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资金
- University of York
- EU
- U.K. EPSRC
- EPSRC [EP/H006710/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H006710/1] Funding Source: researchfish
Preparation of hill complexes using anisotropic 2,5-di(4-alkoxyphenyl)pyridine ligands leads to emissive, liquid-crystalline complexes containing bound CI and dimethyl sulfoxide. Using analogous poly(alkoxy) ligands allows the preparation of bis(2-phenylpyridine)iridium(III) acac complexes, which are also mesomorphic. The observation of liquid crystallinity in octahedral complexes of this type is without precedent.
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