期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 21, 页码 8162-8164出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja202882q
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资金
- Netherlands Organization for Scientific Research (NWO-CW)
- ERC [227897]
- European Research Council (ERC) [227897] Funding Source: European Research Council (ERC)
The interaction between two TEMPO spin centers connected to a photoswitchable overcrowded alkene changes from noncoupled (three-line EPR spectrum) in the trans state, where the two spin centers are separated by similar to 22 angstrom, to strongly coupled (five-line EPR spectrum) in the cis state, where the separation is similar to 7 angstrom, upon photoswitching. Importantly, the performance of the alkene switching unit is essentially unaffected by the spin centers.
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