期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 22, 页码 8470-8473出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja202576e
关键词
-
资金
- MEXT
- Grants-in-Aid for Scientific Research [22790009, 22106522] Funding Source: KAKEN
The torquoselectivity of the 4 pi electrocyclic ring-opening reaction of 2-azetines can be controlled by the Bronsted acidity of the catalyst and the polarity of the solvent. DFT calculations provided insight into the mechanism of this remarkable switch. Anti and syn stereoisomers of alpha,beta-unsaturated amidines were selectively synthesized from ynamides and aldimines in the presence of Tf(2)NH and CSA, respectively.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据