期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 45, 页码 18130-18133出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja208873k
关键词
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资金
- MEXT, Japan
- Grants-in-Aid for Scientific Research [21000006] Funding Source: KAKEN
A chemo- and stereoselective asymmetric direct cross-aldol reaction between aliphatic aldehydes and alpha-chloroaldehydes has been developed as a method for the formation of the sole cross-aldol adduct with both enantio- and diastereocontrol, and either anti- or syn-aldol adducts were obtained in good to excellent stereoselectivities by use of proline or a novel axially chiral amino sulfonamide as catalyst.
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