期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 12, 页码 4160-4163出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja108560e
关键词
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资金
- Boston University
- NIGMS [P50-GM067041]
- NSF [CHE-0619339, CHE-0443618]
Atom transfer radical addition of haloalkanes and alpha-halocarbonyls to olefins is efficiently performed with the photocatalyst Ir[(dF(CF3)ppy)(2)(dtbbpy)]PF6. This protocol is characterized by excellent yields, mild conditions, low catalyst loading, and broad scope. In addition, the atom transfer protocol can be used to quickly and efficiently introduce vinyl trifluoromethyl groups to olefins and access 1,1-cyclopropane diesters.
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