期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 30, 页码 11496-11499出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja205021p
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-
资金
- Deutsche Forschungsgemeinschaft [IRTG 1444, SFB 858]
The beta,beta'-bis(triisopropylsiloxy)phenyl-1, 4-diisocyanide 3 and [Ir(Cp*)Cl(2)](2) were used for the stepwise assembly of the [Ir(Cp*)Cl] cornered molecular square [6](Cl)(4). Synthesis of the tetrakis(diisocyanide) bridged molecular square [Ir(Cp*)Cl(3)](4)(BF(4))(4) [5] (BF(4))(4) followed by cleavage of the O-Si(i-Pr)(3) bonds of the diisocyanide bridges with HCl/i-PrOH led to an intramolecular attack of the liberated hydroxyl groups at the isocyanide carbon atoms with formation of molecular square [6](Cl)(4) featuring four dicarbene linkers.
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