4.8 Article

A Linear-Hyperbranched Supramolecular Amphiphile and Its Self-Assembly into Vesicles with Great Ductility

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 2, 页码 762-764

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ja207924w

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资金

  1. National Basic Research Program [2009CB930400, 2012CB821500]
  2. National Natural Science Foundation of China [21074069, 21174086, 91127047]
  3. Foundation for Author of National Excellent Doctoral Dissertation of China
  4. Fok Ying Tung Education Foundation [114029]

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A linear-hyperbranched supramolecular amphiphile was synthesized through the noncovalent coupling of adamantane-functionalized long alkyl chain (AD-CIV n = 12, 18, 30) and hyperbranched polyglycerol grafted from beta-cyclodextrin (CD-g-HPG) by the specific AD/CD host guest interactions. The obtained supramolecular C-n-b-HPGs self-assembled into unilamellar vesicles with great ductility that could be disassembled readily under a competitive host of beta-CD.

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