期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 21, 页码 8130-8133出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja202594g
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资金
- Deutscher Akademischer Austausch Dienst
- Alfried Krupp von Bohlen und Halbach Foundation
We report the first intermolecular NHC-catalyzed hydroacylation of electron-neutral olefins. Treatment of aromatic aldehydes with cyclopropenes under mild conditions affords valuable acylcyclopropanes in moderate to high yields with an excellent level of diastereocontrol. Preliminary mechanistic studies suggest that product formation occurs via a concerted syn hydroacylation pathway.
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