期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 5, 页码 1162-1164出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja107849y
关键词
-
资金
- ACS PRF [49817-ND1]
- NIH [GM095666, RR08389-01]
- Sloan Foundation
- Beckman Foundation
- Research Corporation
- NSF [CHE-9208463, CHE-9629688]
We report a new method for the formal [3+2] reaction of aryl cyclopropyl ketones with olefins to generate highly substituted cyclopentane ring systems. The key initiation step in this process is the one-electron reduction of the ketone to the corresponding radical anion, which is accomplished using a photocatalytic system comprising Ru(bpy)(3)(2+), La(OTf)(3), and TMEDA.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据