期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 39, 页码 15244-15247出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja205228y
关键词
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资金
- NSFC [20672006, 20821062, 20832002, 20925207, 21002001, GZ419]
- MOST of China [2009CB825300]
Novel C-C bond cleavage of secondary alcohols through Rh(III)-catalyzed beta-carbon elimination directed by a pyridinyl group is reported. A five-membered rhodacycle is proposed as a key intermediate, which undergoes further alkenylation with various olefins. This novel transformation shows high efficiency along with excellent selectivity in mild conditions. A wide range of functionalities are compatible. This study offers a new strategy to carry out C-C bond activation.
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