期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 31, 页码 11924-11927出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2048495
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资金
- 973 Program [2011CB932404, 2011CBA00501]
- NSFC [20821061, 20925102]
- CAS
C3-selective formylation and acylation of free (N-H) indoles under mild conditions can be achieved by using Ru- and Fe-catalyzed oxidative coupling of free (N-H) indoles with anilines, respectively. Both processes are operationally simple, compatible with a variety of functional groups and generally provide the desired products in good yields. (13)C-labeling experiments unambiguously established that the carbonylic carbon in the formylation products originated from methyl group of N-methyl aniline.
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