期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 12, 页码 4240-4242出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1117254
关键词
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资金
- MEXT [18065007, 21550096, 22225004]
- GCOE
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [21550096, 22225004, 18065007] Funding Source: KAKEN
A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.
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