期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 25, 页码 9682-9685出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja203062z
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资金
- MEXT [22106523]
- JSPS
- Uehara Memorial Foundation
- NOVARTIS Foundation (Japan) for the Promotion of Science
- Takeda Science Foundation
- Grants-in-Aid for Scientific Research [22106523, 11J00346, 23655037] Funding Source: KAKEN
Palladium-catalyzed arylative cyclization of propargyl-substituted malonate esters with aryl halides offers a stereoselective approach to alkylidenecyclopropanes. The reaction proceeds by an anti-carbopalladation pathway, which guarantees the exclusive stereocontrol of the resulting double bond. The highly strained as well as densely substituted skeletons of the products facilitate further versatile transformations, which underscores the importance of the products as synthetic intermediates.
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