期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 51, 页码 20724-20727出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2099744
关键词
-
资金
- University of Minnesota
- ACS Petroleum Research Fund [50395-DNI3]
- U.S. DOE [DE-SC002183]
Coordination complexes that pair a zero-valent transition metal (Ni, Co, Fe) and an aluminum(III) center have been prepared. They add to the few examples of structurally characterized metal alanes and are the first reported metallalumatranes. To understand the M-Al interaction and gauge the effect of varying the late metal, the complexes were characterized by X-ray crystallography, electrochemistry, UV-Vis-NIR and NMR spectroscopies, and theoretical calculations. The M-Al bond strength decreases with varying M in the order Ni > Co > Fe.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据