期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 26, 页码 10050-10053出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja203960b
关键词
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资金
- Robert A. Welch Foundation [I-1748]
- W.W. Caruth, Jr. Endowed Scholarship
We report the first total synthesis of (+/-)-trigonoliimine C, a member of a family of structurally complex alkaloids, in 10 steps from tryptamine and 6-methoxytryptamine. Our convergent synthetic strategy relies on a selective oxidative rearrangement of an unsymmetrical 2,2'-bis-tryptamine.
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