期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 8, 页码 2350-2353出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja109676d
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资金
- NRW Graduate School of Chemistry
- DFG
- Alfried Krupp von Bohlen und Halbach Foundation
An efficient Rh(III)-catalyzed oxidative olefination by directed C-H bond activation of N-methoxybenzamides is reported. In this mild, practical, selective, and high-yielding process, the N-O bond acts as an internal oxidant. In addition, simply changing the substituent of the directing/oxidizing group results in the selective formation of valuable tetrahydroisoquinolinone products.
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