期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 28, 页码 10724-10727出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja203520p
关键词
-
资金
- NSF [CHE-0809778]
- Eastman Chemical
We report the ring-opening copolymerization of maleic anhydride with a variety of epoxides catalyzed by a chromium(III) salen complex. Quantitative isomerization of the cis-maleate form of all polymers affords the trans-fumarate analogues. Addition of chain transfer reagents yields low M-n, narrow PDI polymer samples. This method provides access to a range of new unsaturated polyesters with versatile functionality, as well as the first synthesis of high molecular weight poly(propylene fumarate).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据