期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 7, 页码 2060-2063出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja109303z
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资金
- National Natural Science Foundation of China [21043013]
- CIAC
- National Science Foundation [CHE-0718170, CHE-1012258]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1012258] Funding Source: National Science Foundation
Subnanometer-sized copper nanoclusters were prepared by a one-pot procedure based on wet chemical reduction. The structural characteristics of the 2-mercapto-5-n-propylpyrimidine-protected nanoclusters, Cu-n(n <= 8), were determined by mass spectrometry. The Cu nanoclusters displayed apparent luminescence, with dual emissions at 425 and 593 nm, with quantum yields of 3.5 and 0.9%, respectively, and high electrocatalytic activity in the electoreduction of oxygen.
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