期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 5, 页码 1248-1250出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja109562x
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资金
- NIH [GM069559]
- Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, U.S. Department of Energy [DE-AC02-05CH11231]
- Eli Lilly Fellowship
- Deutsche Forschungsgemeinschaft (DFG) [Ta 733/1-1]
The first rhodium-catalyzed arylation of imines proceeding via C-H bond functionalization is reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl-branched N-Boc-amines are formed, and a wide range of functionality is compatible with the reaction.
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