期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 29, 页码 11076-11079出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2040738
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资金
- University of Oxford
- EPSRC
- Diamond Light Source [MT1858]
- EPSRC [EP/H018468/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H018468/1] Funding Source: researchfish
We report the first insertion step at a metal center for the catalytic dehydropolymerization of H3B center dot NMeH2 to form the simplest oligomeric species, H3B center dot NMeHBH2 center dot NMeH2, by the addition of 1 equiv of H3B center dot NMeH2 to [Ir(PCy3)(2)(H)(2)(eta(2)-H3B center dot NMeH2)] [BAr4F] to give [Ir(PCy3)(2)(H)(2)(eta(2)-H3B center dot NMeHBH2 center dot NMeH2)] [BAr4F]. This reaction is also catalytic for the formation of the free linear diborazane, but this is best obtained by an alternative stoichiometric synthesis.
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