期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 3, 页码 389-391出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja108547u
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资金
- UC Irvine Academic Council on Research, Computing, and Library Resources
Secondary benzylic ethers undergo stereospecific substitution reactions with Grignard reagents in the presence of nickel catalysts. Reactions proceed with inversion of configuration and high stereochemical fidelity. This reaction allows for facile enantioselective synthesis of biologically active diarylethanes from readily available optically enriched carbinols.
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