期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 29, 页码 11124-11127出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja205059z
关键词
-
资金
- National Natural Science Foundation
- Ministry of Science and Technology of China [2007CB808001]
- Science and Technology Committee of Shanghai Municipality [10PJ1412200, 09XD1405300]
A novel type of chiral layered supramolecular copolymer with high molecular weight has been assembled from a hydrogen bonded C-6-symmetric zinc porphyrin hexamer and chiral C-3-symmetric pyridine hexadentate linkers driven by multivalent zinc porphyrin-pyridine coordination. UV-vis, circular dichroism, and static light scattering experiments revealed that the formation of the layered supramolecular copolymers is at first dynamically controlled and then becomes thermodynamically controlled.
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