期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 33, 页码 12984-12986出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja206002m
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资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- JSPS
- Grants-in-Aid for Scientific Research [22105001, 10J00248, 22245016] Funding Source: KAKEN
The first catalytic alkynylation of unactivated C(sp(3))-H bonds has been accomplished. The method allows for the straightforward introduction of an ethynyl group into aliphatic acid derivatives under palladium catalysis. This new reaction can be applied to the rapid elaboration of complex aliphatic acids, for example, via azide/alkyne cycloaddition.
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