期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 30, 页码 11508-11511出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja205779b
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资金
- National Institutes of Health (National Institute of General Medical Sciences) [R01-GM094541]
- National Science Foundation [DGE-072540]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0923589] Funding Source: National Science Foundation
Fused BN indoles are an emerging class of boron-containing indole mimics, featuring geometric structure and electophilic aromatic substitution reactivity similar to those of indoles but exhibiting distinct electronic structure, leading to unique optoelectronic properties. Herein we report the synthesis of the parent N-H BN indole and provide a head-to-head comparison of the structural features, pK(a) values, and optoelectronic properties of this hybrid organic/inorganic indole with the classic natural indole.
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