期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 21, 页码 8070-8073出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2001709
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology
- Grants-in-Aid for Scientific Research [22550100, 22105001, 22105002, 22245016] Funding Source: KAKEN
The regioselective carbonylation of unactivated C(sp(3))-H bonds of aliphatic amides was achieved using Ru-3(CO)(12) as a catalyst. The presence of a 2-pyridinylmethylamine moiety in the amide is crucial for a successful reaction. The reaction shows a preference for C-H bonds of methyl groups as opposed to methylene C-H bonds and tolerates a variety of functional groups. The stoichiometric reaction of an amide with Ru-3(CO)(12) gave a dinuclear ruthenium complex in which the 2-pyridinylmethylamino moiety was coordinated to the ruthenium center in an N,N manner.
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