期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 33, 页码 12972-12975出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja205068J
关键词
-
资金
- National Institute of General Medical Sciences [RO1 GM073932]
- Amgen
- Swiss National Science Foundation (SNF)
- NSERC
A highly enantioselective transformation catalyzed by chiral (acyclic diaminocarbene)gold(I) complexes is reported. The enantioselective synthesis of 2-substituted chromenyl pivalates from racemic phenol-substituted propargyl pivalates was developed. Rearrangement of the substrates in the presence of cationic gold gave allene intermediates, whose cyclization resulted in formation of enantioenriched product through a dynamic kinetic asymmetric transformation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据