4.8 Article

Orchestrated Photocatalytic Water Reduction Using Surface-Adsorbing Iridium Photosensitizers

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 31, 页码 11819-11821

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AMER CHEMICAL SOC
DOI: 10.1021/ja201514e

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资金

  1. NSF [CHE- 0949238, CHE-0130903, CHE-1039870]
  2. Division Of Materials Research
  3. Direct For Mathematical & Physical Scien [819860] Funding Source: National Science Foundation

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A series of novel Ir(III) luminophores containing pendant pyridyl moieties that allow for adsorption onto metal surfaces has been synthesized. These new photosensitizer compounds have been evaluated for their efficacy in hydrogen-producing photoreactions. The new complexes are shown to significantly outperform the control photosensitizers without adsorbing moieties.

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