期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 35, 页码 13778-13781出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja206047h
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资金
- Marie Curie Foundation
- Phillip & Patricia Brown for Next Generation Fellowship
- EPSRC
- ERC
- Novartis
- AstraZeneca
- Engineering and Physical Sciences Research Council [EP/I00548X/1] Funding Source: researchfish
- EPSRC [EP/I00548X/1] Funding Source: UKRI
A new strategy for the catalytic enantioselective alpha-arylation of N-acyloxazolidinones with chiral copper(II)-bisoxazoline complexes and diaryliodonium salts is described. The mild catalytic conditions are operationally simple, produce valuable synthetic building blocks in excellent yields and enantioselectivities, and can be applied to the synthesis of important nonsteroidal anti-inflammatory agents and their analogues.
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