期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 1, 页码 190-193出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja210410c
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资金
- JST PRESTO
- Takeda Science Foundation
- Mitsubishi Foundation
- Uehara Memorial Foundation
An aromatic hemiporphyrazine with an 18 pi-electron structure has been synthesized by oxidizing 20 pi-electron 8,10,21,23-tetrahydroxy-28,30-dicarba-27H,29H-hemiporphyrazine with bulky aryl ether substituents. The aromatic nature of the oxidized form was characterized by means of various spectroscopic methods and single-crystal X-ray analysis, with the help of quantum-chemical calculations. The oxidized hemiporphyrazine exhibited an intense absorption at similar to 850 nm. The redox process was found to be reversible.
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