期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 35, 页码 13950-13956出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja109707q
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Na0.40(2)MnO2 belongs to a family of mixed Mn3+ and Mn4+ porous oxides that contains both octahedral and square pyramidal Mn-o units. Neutron and synchrotron radiation studies identify the presence of both sodium ordering (T-Na approximate to 310 K) and Mn charge and orbital ordering. Below T-Na, the centrosymmetric Pbam structure adopts an (a b 4c) supercell of Pnnm symmetry that accommodates a coupled commensurate modulation down the c-axis channels of both Na position and occupancy with Mn valence.
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