期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 6, 页码 1634-1637出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja108894a
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资金
- U.S. National Science Foundation [DMR-0349316]
- Georgetown University
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1106266] Funding Source: National Science Foundation
A rare example of a microporous metal-organic phosphate, [Co(12)(L)(6)(mu(3)-PO(4))(4)(mu(3)-F)(4)(mu-H(2)O)(6)][NO(3)](2) (1), is synthesized by the reaction of a [(eta(5)-C(5)H(5))Fe(II)](+)-functionalized terephthalate ligand with Co(NO(3))(2)center dot 6H(2)O and phosphate and fluoride ions generated from the in situ hydrolysis of hexafluorophosphate. 1 is a cubic, 12-connected, face-centered cubic framework sustained by the linear connection of unprecedented, dodecanuclear truncated tetrahedral coordination clusters.
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