期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 33, 页码 12937-12939出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja204426s
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资金
- Nissan Chemical Industries, Ltd.
- MEXT, Japan
- JSPS
- Grants-in-Aid for Scientific Research [11J03551] Funding Source: KAKEN
The first general method for iron-catalyzed aerobic oxidative kinetic resolution of secondary alcohols was achieved with good to high enantiomeric differentiation (k(rel) = 7-50). Although iron(salan) complex 1 does not catalyze alcohol oxidation, the naphthoxide-bound iron(salan) complex does.
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