期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 19, 页码 7352-7354出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja202605x
关键词
-
资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [19105001, 21350023, 21108502]
- Grants-in-Aid for Scientific Research [19105001, 21350023, 21108502] Funding Source: KAKEN
Reaction of isolable 1,1,4,4-tetrakis[bis(trimethylsilyl)methyl]-1,4-diisopropyltetrasila-2-yne (1) with an equiv amount of 4-dimethylaminopyridine unexpectedly produced the intramolecularly N-coordinated silylene 2 as the primary product. However, 2 was not thermally stable at room temperature in solution and slowly isomerized to silyl anion 3 with a zwitterionic structure via 1,2-hydrogen migration followed by Si-N bond formation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据