期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 24, 页码 9160-9163出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja201139z
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资金
- Natural Sciences and Engineering Research Council
Visible light exposure of films containing silver nanoparticles (AgNPs) shows that the enhanced field around AgNPs in a thin film containing an azo free radical initiator (AIBN) and a triacrylate selectively cross-links the triacrylate within the plasmonic region around the particles. The crosslinked polymer is less soluble than its precursor and behaves as a solubility switch. After the film is developed with ethanol, polymer-encapsulated nanopartides are preserved on the surface. The 8-10 nm polymer structure that encapsulates the particles effectively maps and preserves the morphology of the plasmon field in AgNP-controlled nanostructures.
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